Chlorination of Ketones with Selenium Oxychloride.
نویسندگان
چکیده
منابع مشابه
Solid-phase selenium-catalyzed selective allylic chlorination of polyprenoids: facile syntheses of biologically active terpenoids.
Regioselective halogenation of the terminal isopropylidene unit of different acyclic polyolefinic polyprenoids (farnesyl acetate, geranylgeranyl acetate, squalene, etc.) using NCS/catalytic polymer-supported selenenyl bromide is described; good to excellent yields are obtained (68-96%). The first applications of this protocol include the concise synthesis of bioactive terpenoids 1-3.
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ژورنال
عنوان ژورنال: The Journal of Organic Chemistry
سال: 1964
ISSN: 0022-3263,1520-6904
DOI: 10.1021/jo01035a644